Deuterium isotopomers as a tool in environmental research

This thesis describes the development and the use of quantitative deuterium Nuclear Magnetic Resonance spectroscopy (NMR) as a tool in two areas of environmental research: the study of long term climate-plant interactions and the source tracking of persistent organic pollutant.Long-term interactions between plants and climate will influence climate change during this century and beyond, but cannot be studied in manipulative experiments…

Contents

Introduction
Stable isotopes
General considerations
Definitions
Mechanisms of isotope fractionation
1) Physical fractionations
2) Chemical fractionations
Isotopomers
Measurements of isotope and isotopomer abundance
1) IRMS
3) FTIR
2) NMR
Climate change
Open questions
Tree rings as a proxy for climate (dendroclimatology)
1) Physical characteristics of tree rings
2) Chemical characteristics of tree rings
Persistent organic pollutants in the environment
Definition
Identification of their origin and fate
Results and conclusions
Paper I
Paper II
Paper III…
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Author: Betson, Tatiana

Source: Umea University

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